One is Hollywood's leading star and the other is one of the world's most acclaimed directors.
So it may come as a surprise that they've never worked together before.
But sparks flew when Angelina Jolie and Spanish filmmaker Pedro Almodovar attended a pre Golden Globes event at the weekend.
Angelina was in the middle of an interview at a when she saw the legendary director and ran over to him.
"When are you going to give me work? One day?" she said.
A suprised Pedro replied: "Yes, absolutely. Don’t worry you are young."
However, the actress insisted further: "But do you promise, one day?" to which Pedro repeated his pledged: "This is a commitment in front of the cameras."
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