Earlier in the day she was in über-mum mode, steering her brood through the airport in casual and comfy gear.
Fast forward a few hours and Angelina Jolie was ready to remind us that she's also a smouldering Hollywood siren.
The actress underwent a red re-invention as she dazzled next to partner Brad Pitt at the Japanese premiere of his latest film, Moneyball.
The couple famously take turns to work whilst one acts as homemaker. And the leading lady was taking her supporting role Jolie seriously, having ramped up the glamour a couple of notches.
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She was dressed in a strappy scarlet number which showed off her body art. Finishing off her bombshell look was a slick of killer red lippy.
Both Angelina and Brad signed autographs and posed with fans who were ecstatic to be in the company of the Hollywood power couple.
Away from the cameras, the dynamic duo are in the middle of a legal wrangle with a former employee who claims she was unfairly dismissed.
Ana Charlotiaux, was employed as a bi-lingual secretary at their sprawling Chateau Miraval, their sprawling £35 million estate in Provence.
She was fired after apparently claiming too many days sick leave, and is now trying to reclaim £55,000 in compensation from the actors.
All the news as Duchess Kate's due date draws close...