In keeping with her daring style, the queen of reality TV had poured her million-dollar curves into an Atsuko Kudo latex bodysuit teamed with a transparent gunmetal couture skirt by Ralph & Russo.
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The outfit had the approval of the rapper, who cuddled up to his wife affectionately on the red carpet and gave her a kiss on the shoulder.
Kim was in Britain to pick up her GQ Woman of the Year award. Clearly still in honeymoon mode, Kanye then gave his lady a big kiss when her name was called out.
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The reality star made it clear to the audience that she loves being Mrs West.
When the magazine's editor introduced her as Kim Kardashian, she responded: "It's Kim Kardashian West. I want to thank GQ for making me Woman of the Year, and my husband for making me feel like woman of the year every day."
Dylan Jones had said: "She is simply one of the most famous women in the world. The queen of social media and the queen of TV.
"And since marrying Kanye West in May she has become part of the world's most famous couple. She's Coca Cola famous.. it's Kim Kardashian."
During the ceremony the golden couple were also introduced to Nicole Scherzinger and Lewis Hamilton and caught up with Pharrell Williams.
Prior to the awards, the West family were seen jetting out of LA in style
The previous day the Wests were seen jetting out of LA with their daughter North, who looked adorable in an outfit that was co-ordinated with her mother's, consisting of striped jeans and mini Doc Martens.
Completing Nori's junior rock star look was Chanel clutch valued at $1,450.