Stunning Suki looks to have been taking acting tips from her Hollywood beau Bradley Cooper, as her character makes life difficult for Sam Claflin and Lily Collins' characters Alex and Rosie, two best friends who decide to study in the US together.
SCROLL DOWN FOR VIDEO
Suki Waterhouse in Love, Rosie
Starring Jaime Winstone as one of Alex's housemates, Tamsin Egerton and Christian Cooke, we also have a first look at the new poster for the film.
The British film is based on the bestselling novel Where Rainbows End by Cecelia Ahern.
Lily Collins and Sam Claflin in Love, Rosie
It's a big year for Suki, who was revealed on Friday to have gained a role in the upcoming Divergent sequel, Insurgent.
Production for the film began last week in Atlanta, USA.
Suki, an internationally famous model who is best friends with Cara Delevingne, recently attended the Met Gala 2014, and revealed that the red carpet was "actually very relaxed".
She added: "Not how you'd expect. I felt like I was at a very special occasion. Getting ready I felt like it was my wedding a tiny bit."
Love, Rosie arrives in cinemas on 23 October.