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The pop superstars each took to the stage during the evening which saw Eminem, Depeche Mode and Robbie Williams pick up accolades for their work.
Kylie dressed her petite frame in a shimmering mirror-ball-inspired dress and accessorised her look with large hoop earrings and silver peep-toe heels.
The 45-year-old Australian songstress added a pop of colour to her metallic outfit with bright red lipstick and scarlet nail polish.
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Kylie treated the crowd to tracks from her latest album Kiss Me Once, which is her first album released under Jay Z's record label, Roc Nation.
Shakira then sang at the German awards ceremony, taking to the stage in black fishnet tights and a black bodice with sheer panelling.
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The mother-of-one completed her sleek all-black look with chunky heeled boots.
Singer-songwriter Birdy flew the flag for Britain at the awards, taking home the prize for Best International Solo Artist.
The Hampshire-born singer, who is aged just 17, was honoured for her album Fire Within, which has topped music charts across Europe.