Arriving nearly an hour after her ex-husband, Kym, 37, turned heads as she walked up the red carpet in a dazzling, sequined floor-length gown. The Coronation Street actress was supported by her co-star Antony Cotton and stood by his side as they greeted fans and posed for photographs.
Kym Marsh and Antony Cotton
Jamie, meanwhile, made a solo entrance, looking rugged in a heavy beard and smart black suit. The EastEnders actor, 33, was reunited with his model girlfriend Chloe Peers once inside the star-studded London bash.
Chloe took to Twitter to show just how much fun the couple were having, posting an intimate snap of her kissing Jamie on the cheek.
"Me and my boy @jamielomas1 at the #NTAS London!" wrote Chloe alongside the image, which Jamie retweeted to his thousands of fans.
Kym had her own reason to celebrate as the actress and her co-stars scooped the award for Best Serial Drama, battling it out against EastEnders, Emmerdale and Hollyoaks.
Jamie Lomas and Chloe Peers
Earlier this month, Kym and Jamie were granted a divorce following the breakdown of their marriage. The couple split in October after it was claimed that Kym had had a five-month affair with her co-star Oliver Mellor.
Kym and Jamie, who have a two-year-old daughter Polly, were together for four years before they tied the knot in September 2012. The couple tragically lost their first child Archie Jay Lomas who was born prematurely in 2009.